Get started
Author

Declan G. Gilheany

Observed names: D. G. GILHEANY, D. G. Gilheany, D.G. Gilheany, Declan G Gilheany, Declan Gilheany, Declan G. Gilheany, G Gilheany Declan, Gilheany, D.G., Gilheany, Declan, Gilheany, Declan G.
Observed institutions: University College Dublin, Queen's University Belfast, National University of Ireland, Maynooth, John Wiley & Sons (United Kingdom), Massachusetts Institute of Technology, Newcastle University
ORCID: 0000-0002-1272-4423
Observed ORCID: 0000-0002-1272-4423
OpenAlex ID: A5048128551
Chromium− and Manganese−salen Promoted Epoxidation of Alkenes
2005 · Eoghan M. McGarrigle, Declan G. Gilheany · Chemical Reviews · 870
No d Orbitals but Walsh Diagrams and Maybe Banana Bonds: Chemical Bonding in Phosphines, Phosphine Oxides, and Phosphonium Ylides
1994 · Declan G. Gilheany · Chemical Reviews · 448
The modern interpretation of the Wittig reaction mechanism
2013 · Peter A. Byrne, Declan G. Gilheany · Chemical Society Reviews · 419
PDF
Synthesis of P-Stereogenic Phosphorus Compounds. Asymmetric Oxidation of Phosphines under Appel Conditions
2007 · Enda Bergin, Cormac T. O'Connor, et al. · Journal of the American Chemical Society · 166
Recent progress towards the understanding of metal–salen catalysed asymmetric alkene epoxidation
1998 · Cormac T. Dalton, Kenneth M. Ryan, et al. · Topics in Catalysis · 150
Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride
2011 · Kamalraj V. Rajendran, Declan G. Gilheany · Chemical Communications · 142
PDF
A convenient and mild chromatography-free method for the purification of the products of Wittig and Appel reactions
2012 · Peter A. Byrne, Kamalraj V. Rajendran, et al. · Organic & Biomolecular Chemistry · 95
Unequivocal Experimental Evidence for a Unified Lithium Salt-Free Wittig Reaction Mechanism for All Phosphonium Ylide Types: Reactions with β-Heteroatom-Substituted Aldehydes Are Consistently Selective for cis-Oxaphosphetane-Derived Products
2012 · Peter A. Byrne, Declan G. Gilheany · Journal of the American Chemical Society · 80
PDF
High Enantioselectivities in an (E)-Alkene Epoxidation by Catalytically Active Chromium Salen Complexes. Insight into the Catalytic Cycle
2001 · Adrian M. Daly, Marie F. Renehan, et al. · Organic Letters · 80
Chromium catalysed asymmetric alkene epoxidation. greater selectivity for an E-alkene versus its Z-isomer
1995 · Claudine Bousquet, Declan G. Gilheany · Tetrahedron Letters · 79
Unsymmetrical salen ligands: Synthesis and use in chromium mediated asymmetric epoxidation
1999 · Adrian M. Daly, T. Cormac Dalton, et al. · Tetrahedron Letters · 69
Turning Regioselectivity into Stereoselectivity: Efficient Dual Resolution of P‐Stereogenic Phosphine Oxides through Bifurcation of the Reaction Pathway of a Common Intermediate
2014 · Kirill Nikitin, Kamalraj V. Rajendran, et al. · Angewandte Chemie International Edition · 66
Taming a Functional Group: Creating Air‐Stable, Chiral Primary Phosphanes
2006 · Rachel M. Hiney, Lee J. Higham, et al. · Angewandte Chemie International Edition · 61
Improved resolution methods for (R,R)- and (S,S)-cyclohexane-1,2-diamine and (R)- and (S)-BINOL
2003 · Hans-Jörg Schanz, Michael A Linseis, et al. · Tetrahedron Asymmetry · 60
Chromium–Salen-Mediated Alkene Epoxidation: A Theoretical and Experimental Study Indicates the Importance of Spin-Surface Crossing and the Presence of a Discrete Intermediate
2002 · Peter Brandt, Per-Ola Norrby, et al. · Chemistry - A European Journal · 59
Co-operative ortho-effects on the Wittig reaction. Interpretation of stereoselectivity in the reaction of ortho-halo-substituted benzaldehydes and benzylidenetriphenylphosphoranes
2002 · Eoin C Dunne, Éamonn J Coyne, et al. · Tetrahedron Letters · 59
Identification of a key intermediate in the asymmetric Appel process: one pot stereoselective synthesis of P-stereogenic phosphines and phosphine boranes from racemic phosphine oxides
2012 · Kamalraj V. Rajendran, Declan G. Gilheany · Chemical Communications · 58
PDF
The Mechanism of Phosphonium Ylide Alcoholysis and Hydrolysis: Concerted Addition of the O−H Bond Across the P=C Bond
2016 · Peter A. Byrne, Declan G. Gilheany · Chemistry - A European Journal · 57
PDF
Chromium salen catalysed asymmetric alkene epoxidation. Influence of substituents at the 3,3′-positions on the salen rings
1999 · Kenneth M. Ryan, Claudine Bousquet, et al. · Tetrahedron Letters · 55
First ever observation of the intermediate of phosphonium salt and ylide hydrolysis: P-hydroxytetraorganophosphorane
2014 · Peter A. Byrne, Yannick Ortin, et al. · Chemical Communications · 54
PDF
The synthesis and use in asymmetric epoxidation of metal salen complexes derived from enantiopure trans-cyclopentane- and cyclobutane-1,2-diamine
2003 · Adrian M. Daly, Declan G. Gilheany · Tetrahedron Asymmetry · 53
Degenerate Nucleophilic Substitution in Phosphonium Salts
2014 · Elizabeth V. Jennings, Kirill Nikitin, et al. · Journal of the American Chemical Society · 52
Unsymmetrical chiral salen Schiff base ligands
2005 · Marie F. Renehan, Hans-Jörg Schanz, et al. · Journal of Molecular Catalysis A Chemical · 49
Asymmetric Grignard Synthesis of Tertiary Alcohols through Rational Ligand Design
2017 · Bartosz Bieszczad, Declan G. Gilheany · Angewandte Chemie International Edition · 46
Ligand-based improvement of enantioselectivity in the catalytic asymmetric dihydroxylation of dialkyl substituted olefins
1990 · Tomoyuki Shibata, Declan G. Gilheany, et al. · Tetrahedron Letters · 46
Works count: 186
Citation count: 4,515
H-index: 34
I10-index: 70
Year
Topic
Type