Poly[bis[μ-1,3-bis(diphenylphosphanyl)propane-κ2P:P′]-di-μ-thiocyanato-κ2S:N;κ2N:S-disilver(I)]
Year: 2011
Type: article
Abstract: In the title coordination polymer, [Ag(2)(NCS)(2)(C(27)H(26)P(2))(2)](n), two centrosymmetrically related Ag(+) cations are linked by two thio-cyanate anions into binuclear eight-membered macrocycles. The Ag⋯Ag separation within the macrocycle is 5.4400 (6) Å. The distorted tetra-hedral coordination about each metal atom is completed by the P atoms of two bridging 1,3-bis-(diphenyl-phosphan-yl)propane ligands, forming polymeric ribbons parallel to the a axis.
Authors: Li-Na Cui, Yu-Han Jiang, Li-Li Zhou, Qiong-Hua Jin, Cun-Lin Zhang
Language: Hebrew
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $500
OpenAlex ID: W117807558