Work

The Solid Electrolyte System RbCu4Cl3 ( I 2 − x Cl x ) , 0 ≤ x ≤ 0.40: II . Electrical Conductivity

Year: 1981

Type: article

Abstract: Electrical conductivity has been measured as a function of temperature and composition in the system . Room temperature conductivities uncorrected for deviation of bulk from x‐ray densities, decrease very nearly linearly from 0.39 Ω −1 cm −1 for the stoichiometric composition to 0.28 Ω −1 cm −1 for . Corrections for density could increase these values by about 10%. The enthalpies of activation of motion for the Cu + ions range from 0.112 eV for to 0.117 eV for , indicating that the decrease in conductivity with increasing is caused by the disorder introduced by the replacement of iodide by chloride ions.

Source: Journal of The Electrochemical Society

DOI: 10.1149/1.2127327

Authors: S. Geller, K. Nag, A. K. Ray

Institution: University of Colorado Boulder

Language: English

Topic: Solid-state spectroscopy and crystallography

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: bronze

Funders: National Science Foundation, College of Engineering and Applied Science, University of Wyoming, Division of Materials Research

OpenAlex ID: W1893250308

FWCI: 3.437

Cites:

Cited by: 11

Related to: 10