Work

Copper(I)-Mediated Cross-Coupling Reaction of Carboranyl-lithium with Alkynyllithium：One-Pot Synthesis ofC-Alkynyl-o-carboranes

Year: 2013

Type: article

Abstract: 10 H 12 锂化反应而引入的)过量丁基锂交叉偶联的产物 1-丁基邻碳硼烷(4)和 1,2-二丁基邻碳硼烷(5), 而氯化亚铜参与的邻碳硼烷、端炔、丁基锂的反应体系能够"一锅法"合成炔基邻碳硼烷(产率 33～62%).化合物 5 可由碳硼烷双锂盐与过量的 1-溴丁烷反应获得(产率 84.6%).

Source: Chinese Journal of Organic Chemistry

DOI: 10.6023/cjoc201302007

Authors: Deqian Bian, Yong Nie, Jinling Miao, Yafeng Wang, Zhenwei Zhang

Institution: University of Jinan

Language: English

Topic: Boron Compounds in Chemistry

Subfield: Radiology, Nuclear Medicine and Imaging

Field: Medicine

Domain: Health Sciences

Open Access status: bronze

Funders: National Natural Science Foundation of China, Natural Science Foundation of Shandong Province

Awards: G2302825878, G6759294756