Year: 2008
Type: article
Abstract: C 10 H 14 O 6 , monoclinic, P2 1 (no.4), a = 8.195(2) Å, b = 8.672(2) Å, c = 8.479(1) Å, b = 101.02(1)°,V = 591.5 Å 3 , Z = 2, R gt(F) = 0.051, wRref(F 2 ) = 0.131, T = 293 K. Source of materialThe title compound has been obtained by vitamin B 12-catalysed fragmentation of methyl 2,3-di-O-acetyl-6-deoxy-6-iodo-a-Dmannopyranoside in methanol [1,2].Isolation by chromatography (petroleum ether/ethyl acetate) gave a (67 : 33) mixture of aand b-anomers as colourless oil.Crystallization from ethyl ace-
Authors: Wolfgang Frey, Robert Sardzik, Volker Jäger
Institution: University of Stuttgart
Language: German
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $848
OpenAlex ID: W1965791166