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Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation

Year: 2010

Type: article

Abstract: Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H(2) in less than 60 s at 25 degrees C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.

Source: Journal of the American Chemical Society

DOI: 10.1021/ja101685u

Authors: Sung-Kwan Kim, Won-Sik Han, Tae-Jin Kim, Tae-Young Kim, Suk Woo Nam, Mariusz Mitoraj, Łukasz Piekoś, Artur Michalak, Son-Jong Hwang, Sang Ook Kang

Institutions: California Institute of Technology, Jagiellonian University, Korea University, Korea Institute of Science and Technology

Language: English

Topic: Hydrogen Storage and Materials

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W1969403977

FWCI: 8.816

Cites: 25

Cited by: 189

Related to: 10