Work

Intramolecular N–H⋯Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl 2 complex

Year: 2014

Type: article

Abstract: A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl2 complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.

Source: Chemical Communications

DOI: 10.1039/c4cc02297a

Authors: Jesse V. Gavette, Christina M. Klug, Lev N. Zakharov, Matthew P. Shores, Michael M. Haley, Darren W. Johnson

Institutions: University of Oregon, Colorado State University

Language: English

Topic: Crystallography and molecular interactions

Subfield: Physical and Theoretical Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funder: National Institute of General Medical Sciences

Award: Design of Modular Receptors for Ion and Molecule Recognition