Work

Probabilistic phase space trajectory description for anomalous polymer dynamics

Year: 2011
Type: article
Abstract: It has been recently shown that the phase space trajectories for the anomalous dynamics of a tagged monomer of a polymer--for single polymeric systems and phenomena such as phantom Rouse, self-avoiding Rouse, and Zimm ones, reptation, and translocation through a narrow pore in a membrane, as well as for many polymeric systems such as polymer melts in the entangled regime--are robustly described by the generalized Langevin equation. Here I show that the probability distribution of phase space trajectories for all of these classical anomalous dynamics for single polymers is that of a fractional Brownian motion (fBm), while the dynamics for polymer melts between the entangled regime and the eventual diffusive regime exhibits small but systematic deviations from that of a fBm.
Language: English
Open Access status: bronze
OpenAlex ID: W1974932008
FWCI: 3.484
Cites: 39
Cited by: 19
Related to: 10