Work

cis-Bis(1,10-phenanthroline-κ2N,N′)bis(thiocyanato-κN)magnesium(II)

Year: 2010

Type: article

Abstract: The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro-thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa-hedral geometry containing four N atoms from two 1,10-phenanthroline mol-ecules and two N atoms from two thio-cyanate anions. The asymmetric unit contains one-half mol-ecule, and the complete complex has 2 symmetry.

Source: Acta Crystallographica Section E Structure Reports Online

DOI: 10.1107/s1600536810027054

Authors: Dan Zhao, Fei-Fei Li, Jiao Sha

Institution: Henan Polytechnic University

Language: Hebrew

Topic: Crystal structures of chemical compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $500

Funder: Henan Polytechnic University