Work

Spectroscopic Study of the Thermal Degradation of PVP-Capped Rh and Pt Nanoparticles in H2 and O2 Environments

Year: 2009

Type: article

Abstract: Poly( N -vinylpyrrolidone (PVP)-capped platinum and rhodium nanoparticles (7−12 nm) have been studied with UV−vis, FTIR, and Raman spectroscopy. The absorption bands in the region of 190−900 nm are shown to be sensitive to the electronic structure of surface Rh and Pt atoms as well as to the aggregation of the nanoparticles. In-situ FTIR-DRIFT spectroscopy of the thermal decay of PVP-stabilized Rh and Pt nanoparticles in H 2 and O 2 atmospheres in temperatures ranging from 30 to 350 °C reveals the decomposition of PVP above 200 °C; PVP transforms into a “polyamide−polyene”-like material that is, in turn, converted into a thin layer of amorphous carbon above 300 °C. Adsorbed carbon monoxide was used as a probing molecule to monitor changes of the electronic structure of surface Rh and Pt atoms and accessible surface area. The behavior of surface Rh and Pt atoms with ligated CO and amide groups of pyrrolidones resembles that of surface coordination compounds.

Source: The Journal of Physical Chemistry C

DOI: 10.1021/jp909008z

Authors: Yuri Borodko, Hyun Sook Lee, Sang Hoon Joo, Yawen Zhang, Gabor Somorjai

Institutions: Lawrence Berkeley National Laboratory, University of California, Berkeley

Language: English

Topic: Catalytic Processes in Materials Science

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

Funders: U.S. Department of Energy, Office of Science, Basic Energy Sciences, Division of Materials Sciences and Engineering