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Highly stereoselective methylene transfers onto butanediacetal-protected chiral non-racemic sulfinyl imines using S-ylide technology

Year: 2009

Type: article

Abstract: Diastereomeric ratios of >95 : 5 were obtained when performing methylene transfers onto imines originating from d-mannitol and (S)-(-)-2-methyl-2-propane sulfinamide or ascorbic acid and (R)-(-)-2-methyl-2-propane sulfinamide.

Source: Chemical Communications

DOI: 10.1039/b822779a

Authors: David C. Forbes, Sampada V. Bettigeri, Susanna C. Pischek

Institution: University of South Alabama

Language: English

Topic: Asymmetric Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funder: National Institute of General Medical Sciences

Award: Application of Sulfurane Chemistry in the Assembly of HIV Protease Inhibitors

OpenAlex ID: W1980440974

FWCI: 0.644

Cites: 16

Cited by: 8

Related to: 10