Year: 2014
Type: article
Abstract: The title salt, [K(C18H36N2O6)][Co(CO)4], is an example of a classical carbonyl-metalate. The asymmetric unit contains one cation and one tetrahedral anion, both in general positions. Based on comparison of the four carbonyl C-O bond lengths and C-Co-C angles, the anion is unperturbed by the cation, which is normal for an alkali metal fully encased by a cryptand cage.
Authors: William W. Brennessel, John E. Ellis
Institution: University of Minnesota
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $500
OpenAlex ID: W1987796519