Erratum: Direct determination of rotational correlation time by electron-spin echoesat language @n mapped to a space[J. Chem. Phys. 7 3 , 3507 (1980)]
Year: 1982
Type: erratum
Abstract: The summary that was given of our theoretical computations relating to the phase memory times TM for a slowly tumbling nitroxide was inaccurate.Those results for the slowest decaying mode can be fit to the form: Re E = aril with a, b model dependent.ThUS, for Brownian motion, a"=l 2-13 x 10 3 S-1/2, b"=l t while for approximate free diffusion, a'" 3-12 x 102 S-l13, b'" t.In both cases, the small and large values for a relate to the central and high field extremum spectral regions, respectively, with an intermediate value for the low extremum.For moderate jump, a'" 1 for both extrema and a'" 2 in the central region, while b'" 1.Thus, our spin-echo results follow the moderate jump predictions most closely (when we identify Til'" Re E) conSistent with the CW study (cf.Ref. 4).
Source: The Journal of Chemical Physics
DOI: 10.1063/1.443590
Institution: Cornell University
Language: English
Subfield: Biophysics
Domain: Life Sciences
Open Access status: bronze
OpenAlex ID: W1992544937