Work

Local distortion effects on the spin Hamiltonian parameters of Gd3+substituted into the fluorites

Year: 1975

Type: article

Abstract: The superposition model is used to analyse experimental spin-Hamiltonian parameters for Gd 3+ at cubic, tetragonal, trigonal and rhombic sites in the fluorites. New experimental results are presented which supplement and correct those already in the literature. Superposition model parameters are refined and constraints are determined on the local distortions at the various substituted sites. It is shown that the electronic structure of interstitial fluorines is very different to that of the fluorines on lattice sites.

Source: Journal of Physics C Solid State Physics

DOI: 10.1088/0022-3719/8/23/016

Authors: A Edgar, D J Newman

Institution: Australian National University

Language: English

Topic: Electron Spin Resonance Studies

Subfield: Spectroscopy

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W1992823528

FWCI: 2.309

Cites: 25

Cited by: 41

Related to: 10