Fabrication and low temperature thermoelectric properties of NaxCoO2 (x=0.68 and 0.75) epitaxial films by the reactive solid-phase epitaxy
Year: 2007
Type: article
Abstract: The authors have fabricated NaxCoO2 thin films via lateral diffusion of sodium into Co3O4 (111) epitaxial films (reactive solid-phase epitaxy [Ohta et al., Cryst. Growth Des. 5, 25 (2005)]). The environment of thermal diffusion is key to the control of the sodium content in thin films. From the results of x-ray diffraction and in-plane ρab, the epitaxial growth and the sodium contents of these films were identified. The thermoelectric measurements show a large thermoelectric power similar to that observed in single crystals. The quasiparticle scattering rate is found to approach zero at low temperatures, consistent with the small residual resistivity, indicating high quality of the NaxCoO2 thin films.
Source: Applied Physics Letters
DOI: 10.1063/1.2437131
Authors: W. J. Chang, C. C. Hsieh, T. Y. Chung, S. Y. Hsu, K. H. Wu, T. M. Uen, J.-Y. Lin, J. J. Lin, C.-H. Hsu, Y. K. Kuo, H. L. Liu, M. H. Hsu, Y. S. Gou, J. Y. Juang
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W1999084537