Work

Phase diagram of the penetrable-square-well model

Year: 2011
Type: article
Abstract: We study a system formed by soft colloidal spheres attracting each other via a square-well potential, using extensive Monte Carlo simulations of various nature. The softness is implemented through a reduction of the infinite part of the repulsive potential to a finite one. For sufficiently low values of the penetrability parameter we find the system to be Ruelle stable with square-well–like behavior. For high values of the penetrability the system is thermodynamically unstable and collapses into an isolated blob formed by a few clusters each containing many overlapping particles. For intermediate values of the penetrability the system has a rich phase diagram with a partial lack of thermodynamic consistency.
Language: English
Open Access status: green
OpenAlex ID: W2005048324
FWCI: 1.204
Cites: 28
Cited by: 19
Related to: 10