Year: 1978
Type: article
Abstract: The potentiodynamic response of the Ni/alkaline aqueous solution interface in the region of the hydrated to electrochemical reaction reveals that both species undergo phase transformations. The anodic product from the species involves the formation of three species energetically different which are detected during the electroreduction process. Under well‐defined perturbation conditions, a reasonable set of kinetic parameters pertaining to the anodic process is obtained which is formally interpreted through a consecutive three‐step mechanism of reaction involving a charge transfer, a chemical reaction, and a charge transfer and a proton transfer process. Side reactions involving water take into account the various aging processes of the reaction products.
DOI: 10.1149/1.2131247
Language: English
Topic: Aqueous and Flow Batteries
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W2005956279