Crystal structure of (3R,4R,5R,6S,1'R)-2-benzyl-3-methyl-4,5-O-isopropylidene- dioxy-6-(1'-nitroethyl)-tetrahydro-1,2-oxazine, C17H24N2O5
Year: 2010
Type: article
Abstract: C 17 H 24 N 2 O 5 ,orthorhombic, P2 1 2 1 2 1 (no.19), a =5.461(1)Å, b =17.508(4)Å, c =18.562(3) Å, V =1774.9Å 3 , Z =4, R gt(F) =0.049, wRref(F 2 ) =0.135, T =293 K. Source of materialThe title compound was obtained by reaction of (Z)-4,5-dideoxy-2,3-O-isopropylidene-D-erythro-4-pentenose N-benzyl nitrone with nitroethane in tetrahydrofuran/chloroform in the presence of tetrabutylammonium fluoride trihydrate.The product was purified by MPLC to give aspectrocopically and analytically pure, crystalline compound, m.p. 104 °C,[] a D 20 = -13 (c =0.60, CHCl3).
Authors: Wolfgang Frey, Hua Yang, Volker Jäger
Institution: University of Stuttgart
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $848
OpenAlex ID: W2006414022