A Palladium-Oxo Complex. Stabilization of This Proposed Catalytic Intermediate by an Encapsulating Polytungstate Ligand [J. Am. Chem. Soc. 2005, 127, 11948−11949].
Year: 2008
Type: article
Abstract: In the originally submitted crystallographic file (CIF, Supporting Information) of the complex K 10 Na 3 [Pd(O)(OH)P 2 W 19 O 69 -(OH 2 )]‚16H 2 O (2), one of the potassium cations, K9, had short distances to K10 and four oxygens (O29, O34, O39, and O40) on the polyanion unit.We have now collected a new X-ray single-crystal diffraction dataset, and in our new refinement the original K9 is assigned as the positionally disordered W19B (Figure 1).Here we submit the new CIF file with the corrected assignment of the K9 site.
DOI: 10.1021/ja711078v
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W2009321452