Work

High-resolution dipolar n.m.r. spectra in solids

Year: 1981

Type: article

Abstract: Recent advances in solid state n.m.r. spectroscopy permit obervation of high-resolution dipolar spectra, and thus renewed consideration can be given to solid state n.m.r. as a tool for determining molecular structure. This is illustrated with 13C and 14N single-crystal spectra obtained with both one- and two-dimensional n.m.r. techniques. The successful observation of these spectra is due to the fact that many dipolar interactions are inhomogeneous, and for this reason it is also possible to obtain high-resolution dipolar spectra from powder samples. Methods that accomplish this goal are described and illustrated with 13C -1H dipolar spectra.

Source: Philosophical Transactions of the Royal Society of London Series A Mathematical and Physical Sciences

DOI: 10.1098/rsta.1981.0034

Authors: R. G. Griffin, G. Bodenhausen, R. A. Haberkorn, T. H. Huang, M. Munowitz, R. Osredkar, D. J. Ruben, R. E. Stark, H. Van Willigen

Institutions: Massachusetts Institute of Technology, Harvard University

Language: English

Topic: Advanced NMR Techniques and Applications

Subfield: Spectroscopy

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W2017271616

FWCI: 1.278

Cites:

Cited by: 15

Related to: 10