Work

Kinetics of uncatalyzed isomerization of aliphatic ketoximes

Year: 1986

Type: article

Abstract: Three acyclic, aliphatic ketoximes studied show similar rates of isomerization at room temperature. From the rates of isomerization of one oxime at four temperatures, the thermodynamic activation parameters are calculated and a bimolecular transition state is postulated to account for the large negative entropy of activation.

Source: Tetrahedron Letters

DOI: 10.1016/s0040-4039(00)85164-3

Authors: Robert E. Gawley, Teresa Garcia-Pons

Institution: University of Miami

Language: English

Topic: Chemical Reaction Mechanisms

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $3,610

OpenAlex ID: W2029037985

FWCI:

Cites: 13

Cited by: 2

Related to: 10