Work

Polyelectrolyte-Compression Forces between Spherical DNA Brushes

Year: 2008
Type: article
Abstract: Optical tweezers are employed to measure the forces of interaction within a single pair of DNA-grafted colloids, dependent on the molecular weight of the DNA chains, and the concentration and valence of the surrounding ionic medium. The resulting forces are short range and set in as the surface-to-surface distance between the colloidal cores reaches the value of the brush height. The measured force-distance relation is analyzed by means of a theoretical treatment that quantitatively describes the effects of compression of the chains on the surface of the opposite-lying colloid. Quantitative agreement with the experiment is obtained for all parameter combinations.
Language: English
Field: Chemistry
Open Access status: green
OpenAlex ID: W2038703170
FWCI: 4.669
Cites: 23
Cited by: 53
Related to: 10