Monodentate-Bridged Phosphodiester and Sulfate Complexes: Structural Insights into the Biological Activation of Phosphodiesters, Sulfate, and Sulfate Esters
Year: 2000
Type: article
Abstract: A dinickel(II) complex [Ni2(BPAN)(μ-(PhO)2PO2)2(MeCN)2](ClO4)2 (1) with monodentate bridging diphenyl phosphate groups and a dimanganese(II) compound [Mn2(BPMAN)(μ-SO4)2] (2) with a monodentate bridging sulfate group were synthesized and characterized. The unique bridging modes observed in the structures of these complexes may be relevant to the activation of phosphate and sulfate esters at dimetallic centers in biology.
Source: Inorganic Chemistry
DOI: 10.1021/ic000391i
Institution: Massachusetts Institute of Technology
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W2046564932