Work

Strong, Localized, and Directional Hydrogen Bonds Fluidize Ionic Liquids

Year: 2008
Type: article
Abstract: Opposite effect of hydrogen bonding: Whereas molecular liquids are stabilized, ionic liquids can be fluidized by hydrogen bonds. Highly directional H bonds introduce “defects” into the Coulomb network resulting in reduced melting points and decreased viscosities. This is shown by the mid- and far-FTIR spectra of two ionic liquids. (Structure in black: all H bonds are possible, structure in white: methyl group prevents one H bond.)
Language: English
Subfield: Catalysis
Open Access status: bronze
OpenAlex ID: W2047850266
FWCI: 8.598
Cites: 29
Cited by: 433
Related to: 10