Work

Chemical Reactivity of PF[sub 5] and LiPF[sub 6] in Ethylene Carbonate/Dimethyl Carbonate Solutions

Year: 2001

Type: article

Abstract: The thermal decomposition of in a mixture (1:1 molar ratio) of ethylene carbonate (EC)/dimethyl carbonate (DMC) at 85°C is compared to the reaction between EC/DMC and gas. Both produce a brown solution and gaseous products. The reaction products from and in 1:1 EC/DMC, detected by gas chromatography, are similar. Proton nuclear magnetic resonance provided evidence for the presence of oligoether carbonates in the reaction products. © 2001 The Electrochemical Society. All rights reserved.

Source: Electrochemical and Solid-State Letters

DOI: 10.1149/1.1353158

Authors: S. E. Sloop, J. K. Pugh, S. Wang, J. B. Kerr, K. Kinoshita

Institution: Lawrence Berkeley National Laboratory

Language: English

Topic: Advancements in Battery Materials

Subfield: Electrical and Electronic Engineering

Field: Engineering

Domain: Physical Sciences

Open Access status: bronze

Funders: U.S. Department of Energy, Argonne National Laboratory, Lawrence Berkeley National Laboratory

Awards: G1398330795, G1614572836, G1643223109