Work

Solid-like dynamics in ultrathin films of polymeric liquids

Year: 2003
Type: article
Abstract: In this letter, we demonstrate that, at mesoscales, nonferroelectric liquid films of poly(dimethyl siloxane) exhibit significant electrostriction not present in the corresponding bulk state. Remarkably, the observed electrostrictive effect has a response time <20 μs in contrast to >5 ms recorded in conventional bulk (ferroelectric) polymers. The emergence of this fast electrostrictive strain in thin films is explained in terms of the amalgamation of two contrasting dynamic features—the influence of a highly mobile, viscous layer (at the air/film interface) on the less-mobile, but fast responding, solid-like layer at the film/substrate interface. The effect is observed for thickness below 200 nm.
Language: English
Open Access status: green
OpenAlex ID: W2051870868
FWCI: 0.264
Cites: 14
Cited by: 2
Related to: 10