Oxidative Degradation of the Carbothioate Herbicide, Molinate, Using Nanoscale Zero-Valent Iron
Year: 2004
Type: article
Abstract: Degradation of the carbothiolate herbicide, molinate, has been investigated in oxic solutions containing nanoscale zero-valent iron particles and found to be effectively degraded by an oxidative pathway. Both ferrous iron and superoxide (or, at pH < 4.8, hydroperoxy) radicals appearto be generated on corrosion of the zero-valent iron with resultant production of strongly oxidizing entities capable of degrading the trace contaminant.
DOI: 10.1021/es035157g
Authors: Sung Hee Joo, Andrew J. Feitz, T. David Waite
Institution: UNSW Sydney
Language: English
Subfield: Environmental Engineering
Field: Environmental Science
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W2059018786
