Work

Oxidative Carbon−Carbon Bond Formation via Allyldimethylsilyl Enol Ethers

Year: 2009

Type: article

Abstract: A method for the oxidative alkylation of ketones through intramolecular allyl-group transfer within preformed allyldimethylsilyl enol ethers is reported. A number of examples are detailed, including a study into the effects of resident sterocenters within cyclic enol ethers.

Source: Organic Letters

DOI: 10.1021/ol902400q

Authors: Leah C. Konkol, Brian T. Jones, Regan J. Thomson

Institution: Northwestern University

Language: English

Topic: Organic Chemistry Synthesis Methods

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funder: National Institute of General Medical Sciences

Award: New Methods for the Concise Synthesis of Bioactive Polycyclic Molecules