Work

Direct synthesis of organic carbonates by oxidative carboxylation of olefins catalyzed by metal oxides: developing green chemistry based on carbon dioxide

Year: 2000

Type: article

Abstract: In this paper we report on the ‘oxidative-carboxylation’ of olefins catalysed by either transition metal complexes or metal oxides. We discuss the oxidation mechanism under homogeneous and heterogeneous conditions. In the former case the process is driven by co-ordination to the metal centre, in the latter a radical reaction takes place. The yield of carbonate is strongly dependent on the catalyst used. Copyright © 2000 John Wiley & Sons, Ltd.

Source: Applied Organometallic Chemistry

DOI: 10.1002/1099-0739(200012)14:12<799::aid-aoc82>3.0.co;2-8

Authors: Michele Aresta, Angela Dibenedetto, Immacolata Tommasi

Institution: University of Bari Aldo Moro

Language: English

Topic: Carbon dioxide utilization in catalysis

Subfield: Process Chemistry and Technology

Field: Chemical Engineering

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W2066490078

FWCI: 3.481

Cites: 20

Cited by: 89

Related to: 9