Inside Cover: CH Activation in S‐Alkenyl Sulfoximines: An Endo 1,5‐Hydrogen Migration (Angew. Chem. Int. Ed. 28/2012)
Year: 2012
Type: article
Abstract: A Hydride Transfer that occurs by a 6-endo-trig process initiates an intramolecular redox reaction. In their Communication on page 7016 ff., M. Harmata et al. demonstrate that heating of N-alkyl-, N-allyl-, and N-benzyl-substituted S-alkenyl sulfoximines results in the formation of NH-S-alkyl sulfoximines under appropriate conditions. The intermediates in the reaction can also give access to four- and six-membered heterocyclic rings and a new class of chiral dienes.
Institution: University of Missouri
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W2068725996