Work

Mononuclear Copper Complex-Catalyzed Four-Electron Reduction of Oxygen

Year: 2010

Type: article

Abstract: A mononuclear Cu(II) complex acts as an efficient catalyst for four-electron reduction of O(2) to H(2)O. Its reduction by a ferrocene derivative (Fc*) and reaction with O(2) leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc* in the presence of protons to regenerate the Cu(II) complex.

Source: Journal of the American Chemical Society

DOI: 10.1021/ja100538x

Authors: Shunichi Fukuzumi, Hiroaki Kotani, Heather R. Lucas, Kaoru Doi, Tomoyoshi Suenobu, Ryan L. Peterson, Kenneth D. Karlin

Institutions: Ewha Womans University, Johns Hopkins University, Japan Science and Technology Agency, The University of Osaka

Language: English

Topic: Metal-Catalyzed Oxygenation Mechanisms

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funder: National Institute of General Medical Sciences

Awards: Bioinorganic Copper Coordination Chemistry, BIOINORGANIC COPPER COORDINATION CHEMISTRY, G5654475832

OpenAlex ID: W2072969152

FWCI: 7.239

Cites: 27

Cited by: 146

Related to: 10