Year: 2010
Type: article
Abstract: We have investigated hydroxylation and water adsorption on α-Fe 2 O 3 (0001) at water vapor pressures up to 2 Torr and temperatures ranging from 277 to 647 K (relative humidity (RH) ≤ 34%) using ambient-pressure X-ray photoelectron spectroscopy (XPS). Hydroxylation occurs at the very low RH of 1 × 10 −7 % and precedes the adsorption of molecular water. With increasing RH, the OH coverage increases up to one monolayer (ML) without any distinct threshold pressure. Depth profiling measurements showed that hydroxylation occurs only at the topmost surface under our experimental conditions. The onset of molecular water adsorption varies from ∼2 × 10 −5 to ∼4 × 10 −2 % RH depending on sample temperature and water vapor pressure. The coverage of water reaches 1 ML at ∼15% RH and increases to 1.5 ML at 34% RH.
DOI: 10.1021/jp909876t
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: green
Funder: National Science Foundation
OpenAlex ID: W2076843280