Work

Carbon and hydrogen isotope fractionation resulting from anaerobic methane oxidation

Year: 1988

Type: article

Abstract: Methane oxidation in the anoxic sediments of Skan Bay, Alaska resulted in fractionation of carbon and hydrogen isotopes in methane. Isotope fractionation factors were estimated by fitting methane concentration, δ13C‐CH4, and δD‐CH4 data with depth distributions predicted by an open system, steady state model. Assuming that molecular diffusion coefficients for 12CH4, 13CH4, and12CH3D are identical, the predicted fractionation factors were 1.0088±0.0013 and 1.157±0.023 for carbon and hydrogen isotopes, respectively. If aqueous diffusion coefficients for the different isotopic species of methane differ significantly, the predicted fractionation factors are larger by an amount proportional to the diffusion isotope effect.

Source: Global Biogeochemical Cycles

DOI: 10.1029/gb002i003p00279

Authors: M. J. Alperin, W. S. Reeburgh, M. J. Whiticar

Institutions: University of North Carolina at Chapel Hill, Federal Institute for Geosciences and Natural Resources, University of Alaska Fairbanks

Language: English

Topic: Methane Hydrates and Related Phenomena

Subfield: Environmental Chemistry

Field: Environmental Science

Domain: Physical Sciences

SDG: Climate action

Open Access status: bronze

Funder: National Science Foundation