Year: 1968
Type: article
Abstract: Evidence for a linea r dimer Li,F, ha s been obtaine d by ex te nding the spe c tral meas ure me nts for matrix isolate d lithium flu orid e into the far infrared reg ion.The \'apors from so lid 6LiF 7LiF and "LiF/'LiF mixtures were depos ited in argon matri ces at liquid hydrogen tempe ra tures.Vibrat';onal assignments we re made o n th e basis of th e following linear spec ies: "Li,F" 7Li,F" fi.7Li , F, and 7. (;Li , F".Although the specifi c geo me try of th e dim e r co uld not b e de te rmin ed , a norm a l coordinate analys is s upported th e spectral int e rpre tation of a lin ear s tru cture (e x v).
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
OpenAlex ID: W2093803605