Work

Water Oxidation Catalyzed by a Dinuclear Mn Complex: A Functional Model for the Oxygen‐Evolving Center of Photosystem II

Year: 2005

Type: article

Abstract: A highly specific and catalytic oxidation of water occurs when using a dinuclear Mn complex of a mononegative carboxylate-containing pentadentate ligand (see scheme). Isotope-labeling experiments coupled with membrane inlet mass spectrometry show that one oxygen atom in the evolved O2 molecule is derived from water and the other from the oxidant.

Source: Angewandte Chemie International Edition

DOI: 10.1002/anie.200502114

Authors: Allan K. Poulsen, Annette Rompel, Christine J. McKenzie

Institution: University of Southern Denmark

Language: English

Topic: Metal-Catalyzed Oxygenation Mechanisms

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W2100429960

FWCI: 7.575

Cites: 20

Cited by: 215

Related to: 10