Work

Structural Effects of Solvents on the Breathing of Metal–Organic Frameworks: An In Situ Diffraction Study

Year: 2008

Type: article

Abstract: Breathing space: Time-resolved diffraction studies of the breathing of metal–organic frameworks in the presence of liquids reveal rapid exchange of one guest molecule by another. In some cases this occurs by direct exchange (as shown for water by pyridine), in others with the transient appearance of crystalline intermediates corresponding to partially expanded forms.

Source: Angewandte Chemie International Edition

DOI: 10.1002/anie.200705607

Authors: Franck Millange, Christian Serre, Nathalie Guillou, Gérard Férey, Richard I. Walton

Institutions: Centre National de la Recherche Scientifique, Université de Versailles Saint-Quentin-en-Yvelines, Institut Lavoisier de Versailles, University of Warwick

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W2113663701

FWCI: 14.49

Cites: 40

Cited by: 214

Related to: 10