Work

A dual catalytic strategy for carbon–phosphorus cross-coupling via gold and photoredox catalysis

Year: 2014

Type: article

Abstract: dual gold and photoredox catalysis is described. The reaction proceeds smoothly at room temperature in the absence of base and/or additives, and offers an efficient approach to arylphosphonates. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes coupling with the H-phosphonate nucleophile.

Source: Chemical Science

DOI: 10.1039/c4sc03092c

Authors: Ying He, Hongmiao Wu, F. Dean Toste

Institutions: Nanjing University, University of California, Berkeley, University of California System

Language: English

Topic: Radical Photochemical Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: National Natural Science Foundation of China, National Institutes of Health, National Institute of General Medical Sciences

Awards: G1509652373, Catalytic Methods for Carbon-Carbon and Carbon-Heteroatom Bond Formation