Work

Inside Cover: A Minimalist NMR Approach for the Structural Revision of Mucoxin (Chem. Eur. J. 46/2010)

Year: 2010
Type: article
Abstract: Puzzle solved When the spectra of the synthesized structure of mucoxin, a natural product from the Annonaceous acetogenin family, did not match that of the isolated sample, the reason was not as obvious as one might hope. With the proper use of trends observed in NMR chemical shift correlations and coupling constants, as determined using a series of carefully chosen synthesized diastereomers of the possible structure, one can solve the structural puzzle as described by C. Vasileiou, B. Borhan et al. in their Full Paper on p. 13749 ff.
Language: English
Subfield: Spectroscopy
Field: Chemistry
Open Access status: bronze
OpenAlex ID: W2115594453
FWCI:
Cites:
Cited by:
Related to: 10