Work

Soluble Lanthanide Salts (LnCl 3 ⋅2 LiCl) for the Improved Addition of Organomagnesium Reagents to Carbonyl Compounds

Year: 2006

Type: article

Abstract: Easy-to-prepare solutions of LnCl3⋅2 LiCl (Ln=La, Ce, Nd) (0.3–0.5 M in THF) are a unique source of soluble lanthanide salts with versatile applications in organic synthesis. These salts can serve as promoters or catalysts for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines.

Source: Angewandte Chemie International Edition

DOI: 10.1002/anie.200502485

Authors: Arkady Krasovskiy, Felix Kopp, Paul Knochel

Institution: Ludwig-Maximilians-Universität München

Language: English

Topic: Coordination Chemistry and Organometallics

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W2119413610

FWCI: 6.335

Cites: 27

Cited by: 347

Related to: 10