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Electrochemical Behavior and Antioxidant and Prooxidant Activity of Natural Phenolics

Year: 2007
Type: article
Abstract: We have investigated the electrochemical oxidation of a number natural phenolics (salicylic acid, m-hydroxybenzoic acid, p-hydroxybenzoic acid, protocatechuic acid, o-coumaric acid, m-coumaric acid, p-coumaric acid, caffeic acid, quercetin and rutin) using cyclic voltammetry. The antioxidant properties of these compounds were also studied. A structural analysis of the tested phenolics suggests that multiple OH substitution and conjugation are important determinants of the free radical scavenging activity and electrochemical behavior. Compounds with low oxidation potentials (Epa lower than 0.45) showed antioxidant activity, whereas compounds with high Epa values (>0.45) act as prooxidants.
Source: Molecules
Language: English
Field: Chemistry
Open Access status: gold
Estimated APC paid: $3,258
OpenAlex ID: W2122329077
FWCI: 4.09
Cites: 38
Cited by: 336
Related to: 9