Work

Direct Assessment of Electron Delocalization Using NMR Chemical Shifts

Year: 2009

Type: article

Abstract: Probe it: The new BLW-IGLO approach evaluates the magnetic responses of molecules in which conjugative interactions are “disabled” (see picture, red bonds). The NMR spectroscopy parameters of the localized structures provide ideal non-aromatic olefinic hydrogen δ(1H) references for the fully conjugated systems.

Source: Angewandte Chemie International Edition

DOI: 10.1002/anie.200905390

Authors: Stephan N. Steinmann, Daniel F. Jana, Judy I.‐C. Wu, Paul von R. Schleyer, Yirong Mo, Clémence Corminboeuf

Institutions: École Polytechnique Fédérale de Lausanne, University of Georgia, Western Michigan University

Language: English

Topic: Synthesis and Properties of Aromatic Compounds

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W2125487112

FWCI: 3.547

Cites: 38

Cited by: 51

Related to: 10