Work

Decoupled Control of Carbon Nanotube Forest Density and Diameter by Continuous‐Feed Convective Assembly of Catalyst Particles

Year: 2013

Type: article

Abstract: The widespread potential application of vertically aligned carbon nanotube (CNT) forests have stimulated recent work on large-area chemical vapor deposition growth methods, but improved control of the catalyst particles is needed to overcome limitations to the monodispersity and packing density of the CNTs. In particular, traditional thin-film deposition methods are not ideal due to their vacuum requirements, and due to limitations in particle uniformity and density imposed by the thin-film dewetting process. Here, a continuous-feed convective self-assembly process for manufacturing uniform mono- and multi-layers of catalyst particles for CNT growth is presented. Particles are deposited from a solution of commercially available iron oxide nanoparticles, by pinning the meniscus between a blade edge and the substrate. The substrate is translated at constant velocity under the blade so the meniscus and contact angle remain fixed as the particles are deposited on the substrate. Based on design of the particle solution and tuning of the assembly parameters, a priori control of CNT diameter and packing density is demonstrated. Quantitative relationships are established between the catalyst size and density, and the CNT morphology and density. The roll-to-roll compatibility of this method, along with initial results achieved on copper foils, suggest promise for scale-up of CNT forest manufacturing at commercially relevant throughput.

Source: Small

DOI: 10.1002/smll.201202878

Authors: Erik S. Polsen, Mostafa Bedewy, A. John Hart

Institution: University of Michigan

Language: English

Topic: Carbon Nanotubes in Composites

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: bronze