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A Germanium Zeotype Containing Intratunnel Transition Metal Complexes

Year: 1999

Type: article

Abstract: A new zeolite-type structure is adopted by (NH(4))(+)[M(NH(3))(2)](+)(Ge(9)O(19))(2-) (M=Cu, Ag; shown in the picture). These compounds are the first microporous germanates containing a transition metal complex inside their tunnels. The large separation between the metal centers and the unhindered access of reactants to these active sites through uniformly sized channels make these materials a good point of departure for designing new catalysts.

Source: Angewandte Chemie International Edition

DOI: 10.1002/(sici)1521-3773(19990816)38:16<2436::aid-anie2436>3.0.co;2-w

Authors: Concepción Cascales, Enrique Gutiérrez-Puebla, Marta Iglesias, M. Angeles Monge, Caridad Ruíz-Valero

Institutions: Consejo Superior de Investigaciones Científicas, Instituto de Ciencia de Materiales de Madrid

Language: English

Topic: Zeolite Catalysis and Synthesis

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W2132280274

FWCI: 4.567

Cites:

Cited by: 64

Related to: 10