Work

Quantitative Evaluation of Anion–π Interactions in Solution

Year: 2008

Type: article

Abstract: Anions included: A series of meso-tetraaryl calix[4]pyrrole receptors have been used as a model system to quantify chloride–π interactions in solution (see picture; green balls are chloride ions). The free energy values are generally indicative of a repulsive interaction; their magnitude depends on the substituent on the aromatic ring.

Source: Angewandte Chemie International Edition

DOI: 10.1002/anie.200800636

Authors: Guzmán Gil‐Ramírez, Eduardo C. Escudero‐Adán, Jordi Benet‐Buchholz, Pablo Ballester

Institutions: Institut Català d'Investigació Química, Institució Catalana de Recerca i Estudis Avançats

Language: English

Topic: Supramolecular Chemistry and Complexes

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W2133182004

FWCI: 8.627

Cites: 33

Cited by: 214

Related to: 7