Work

Synthesis and structure of a hydrogenated zinc hemiporphyrazine

Year: 2012

Type: article

Abstract: Palladium-catalyzed hydrogenation of an octahedral zinc trans-ditriflate hemiporphyrazine "HpH2Zn(OTf)2" furnishes a new macrocycle "HpH6Zn(OTf)2". This reaction is fully reversible upon heating in nitrobenzene, and the conversion is easily monitored by changes in color and fluorescence properties. The reversible cycling between these molecules may find future applications in hemiporphyrazine-based catalysts and/or hydrogen storage devices.

Source: Chemical Communications

DOI: 10.1039/c2cc37151k

Authors: Sabrina M. Huber, Guillaume Mata, Anthony Linden, Nathan W. Luedtke

Institution: University of Zurich

Language: English

Topic: Porphyrin and Phthalocyanine Chemistry

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W2163112246

FWCI:

Cites: 15

Cited by: 5

Related to: 10