{μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)gadolinium(III)
Year: 2010
Type: article
Abstract: In the title dinuclear complex, [CuGd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is located in the inner N(2)O(2) cavity of the Schiff base ligand and adopts a distorted square-planar geometry. The Gd(III) ion is ten-coordinate being bound to ten O atoms, four from the Schiff base ligand and six from three bidentate nitrate anions. The Cu(II) and Gd(III) ions are linked by two phenolate O atoms of the Schiff base ligand, with a separation of 3.5185 (9) Å.
Authors: Christopher Chan, Xiaoping Yang, Richard A. Jones, Bradley J. Holliday, Julie M. Stanley
Institution: The University of Texas at Austin
Language: Hebrew
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $500
OpenAlex ID: W2166213376