Work

Inclusion Complexes Oriented in Thermotropic Liquid-Crystalline Solvents Studied with Carbon-13 NMR

Year: 2003

Type: article

Abstract: The inclusion complex of cryptophane-A and chloroform dissolved in two nonchiral liquid-crystalline environments was investigated via 13 C NMR. Stable solutions of oriented complexes were prepared using aromatic (ZLI 1132) and aliphatic (ZLI 1695) thermotropic nematic liquid crystals as solvents; ordering of the complexes was manifested by the 1 H− 13 C dipolar splitting of the 13 C resonance of labeled chloroform. In both solutions, the dipolar splitting for the bound ligands was substantially larger than that obtained for the free ligands, indicating a significant increase in ligand ordering upon complexation despite the absence of direct contact with the oriented solvent molecules. A similar enhancement in ordering was observed for complexed ligands compared to that for free ligands in both liquid-crystalline solvents. Also, the application of heteronuclear decoupling to the ZLI 1695 solution resulted in a reduced line width for the bound 13 C chloroform resonance, suggesting that a significant component of the observed line broadening may originate from intermolecular couplings between host and guest molecules. These results demonstrate the potential for using restored dipolar couplings to investigate structural and dynamical aspects of inclusion complexes in solution.

Source: The Journal of Physical Chemistry B

DOI: 10.1021/jp030431e

Authors: Malgorzata Marjanska, Boyd M. Goodson, Franca Castiglione, Alexander Pines

Institutions: Southern Illinois University Carbondale, Lawrence Berkeley National Laboratory, University of California, Berkeley

Language: English

Topic: Advanced NMR Techniques and Applications

Subfield: Spectroscopy

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funders: U.S. Department of Energy, Office of Science, Basic Energy Sciences

Awards: G1398330795, G1643223109, G2787076192, G301008592, G3444594369