Work

Enhancement of Thermoelectric Performance of Sr 0.9 Ba 0.1 Ti 0.8 Nb 0.2 O 3 Ceramics by A-Site Cation Nonstoichiometry

Year: 2015

Type: article

Abstract: Sr 0.9 Ba 0.1-x Ti 0.8 Nb 0.2 O 3 ceramics (x=0, 0.01, 0.02 and 0.05) are prepared by solid state reaction, whose thermoelectric properties are investigated from 323 K to 1073 K. By introducing A-site nonstoichiometry, the absolute See-beck coefficient is enhanced, while the electrical resistivity is surprisingly reduced due to the significantly enhanced carrier mobility. These results are dramatic in thermoelectric materials, effectively enhancing the power factor. Moreover, the thermal conductivity is reduced, thus the thermoelectric performance of Sr 0.9 Ba 0.1 Ti 0.8 Nb 0.2 O 3 ceramic is significantly enhanced by A-site nonstoichiometry.

Source: Chinese Physics Letters

DOI: 10.1088/0256-307x/32/3/037201