Work

MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification

Year: 2013

Type: article

Abstract: The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal-organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is found using the Ni@(Fe)MIL-101 catalyst than reported for molecular nickel diimino complexes.

Source: Journal of the American Chemical Society

DOI: 10.1021/ja312120x

Authors: Jerome Canivet, Sonia Aguado, Yves Schuurman, David Farrusseng

Institutions: Centre National de la Recherche Scientifique, Institut de Recherches sur la Catalyse et l'Environnement de Lyon

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W2321905829

FWCI: 11.26

Cites: 62

Cited by: 277

Related to: 10