Work

Synthesis of Surface-Functionalized WS2 Nanosheets and Performance as Li-Ion Battery Anodes

Year: 2012

Type: article

Abstract: Separation of bulk tungsten disulfide (or WS2) into few-layer two-dimensional (2-D) crystals is of interest because of their high surface area for certain chemical processes and size-dependent optical and electronic characteristics. Herein, we demonstrate a process that involves the physical separation of weakly bonded WS2 layers by use of a strong acid treatment (chlorosulfonic acid) at 2 mg/mL, followed by quenching in deionized (DI) water. X-ray photoelectron spectroscopy of the superacid-treated WS2 suggests the formation of W-O type bonds, signifying oxidation of tungsten and reduction of the sulfur phase. Thermogravimetric analysis showed a three-phase weight-loss pattern, suggesting acid functionalization of WS2 surfaces. We also studied the electrochemical behavior of an acid-treated WS2 anode in a lithium half-cell configuration that showed a three-step charge-discharge behavior, characteristic of a conversion reaction. The electrochemical capacity was 118 mAh/g after 50 cycles.

Source: The Journal of Physical Chemistry Letters

DOI: 10.1021/jz300480w

Authors: R. Bhandavat, L. David, G. Singh

Institution: Kansas State University

Language: English

Topic: Advancements in Battery Materials

Subfield: Electrical and Electronic Engineering

Field: Engineering

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: hybrid

Estimated APC paid: $4,500